Issue 9, 1975

Controlled radical production and dimerisation induced by cobalt(III)

Abstract

Rapid intramolecular oxidation of the car-banion (NH3)5CoN[triple bond, length half m-dash]C[C with combining macron]HPh generated in [(NH3)5Co-N[triple bond, length half m-dash]C–CH2Ph]3+ yields the nitrile radical which immedi-ately dimerises to stilbene dinitrile.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 324-325

Controlled radical production and dimerisation induced by cobalt(III)

I. I. Creaser and A. M. Sargeson, J. Chem. Soc., Chem. Commun., 1975, 324 DOI: 10.1039/C39750000324

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