Irradiation of 1,4-dimethoxytriptycene in methanol or benzene with u.v. light gave 5-methoxybenz[a]-aceanthrylene; the result with methanol shows that a carbene is not an intermediate in the rearrangement.
R. O. Day, V. W. Day, S. J. Fuerniss and D. M. S. Wheler, J. Chem. Soc., Chem. Commun., 1975, 296 DOI: 10.1039/C39750000296
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