Issue 7, 1975
From the journal:

Journal of the Chemical Society, Chemical Communications

Addition of hexafluorobut-2-yne to co-ordinated 1,3-dienes; crystal structures of the adducts [Ru(CO)2{P(OCH2)3CMe}(C6H8)(C4F6)2] and [Fe(CO)2{P(OCH2)3CMe}(C7H8)(C4F6)2]

Martin Bottrill,   Richard Goddard,   Michael Green,   Russell P. Hughes,   Malcolm K. Lloyd,   Brian Lewis  and  Peter Woodward  

Abstract

Hexafluorobut-2-yne forms 1 : 1 adducts with tricarbonyl(butadiene or 2,3-dimethylbutadiene)iron and tricarbonyl-(o-styryldiphenylphosphine)iron, whereas tri-carbonyl(cyclohexa-1,3-diene)-iron and -ruthenium, and tricarbonyl(cycloheptatriene)iron form unusual 1 : 2 adducts identified by X-ray crystallography.

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Article information

DOI
https://doi.org/10.1039/C39750000253
Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 253-255

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Addition of hexafluorobut-2-yne to co-ordinated 1,3-dienes; crystal structures of the adducts [Ru(CO)2{P(OCH2)3CMe}(C6H8)(C4F6)2] and [Fe(CO)2{P(OCH2)3CMe}(C7H8)(C4F6)2]

M. Bottrill, R. Goddard, M. Green, R. P. Hughes, M. K. Lloyd, B. Lewis and P. Woodward, J. Chem. Soc., Chem. Commun., 1975, 253 DOI: 10.1039/C39750000253

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