A transient radical cation with a three-electron bond between the two sulphur atoms in the 1,4-positions is formed upon oxidation of 1,4-dithian by OH radicals in aqueous solutions at low solute concentration.
D. Bahnemann and K. Asmus, J. Chem. Soc., Chem. Commun., 1975, 238 DOI: 10.1039/C39750000238
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