An investigation of the reactions of methylene with cis-but-2-ene, in excess of nitrogen, as a function of temperature yielded results which are interpreted in terms of a high (ca. 38 kJ mol–1) energy separation between triplet and singlet methylene.
H. M. Frey and G. J. Kennedy, J. Chem. Soc., Chem. Commun., 1975, 233 DOI: 10.1039/C39750000233
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