The acid-catalysed rearrangement of the nor-bornenyl α-bromo sulphoxides (2) results in a cleavage-recombination sequence ultimately generating the regioselective addition product of dehydronorcamphor and methanesulphenyl bromide.
J. C. Philips, M. Penzo and G. T. S. Lee, J. Chem. Soc., Chem. Commun., 1975, 107 DOI: 10.1039/C39750000107
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