Issue 3, 1975

Activation of carbon diselenide by transition-metal complexes selenocarbonyl derivatives of chromium and manganese

Abstract

Carbon diselenide react in the presence of PPh3 with (π-C5H5)Mn(CO)2(THF) or (π-C6H5CO2Me)-Cr(CO)2(THF) to give (π-C5H5)Mn(CO)2(CSe) and (π-C6H5CO2Me)Cr(CO)2(CSe), the first examples of transitionmetal selenocarbonyls.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 103-104

Activation of carbon diselenide by transition-metal complexes selenocarbonyl derivatives of chromium and manganese

I. S. Butler, D. Cozak and S. R. Stobart, J. Chem. Soc., Chem. Commun., 1975, 103 DOI: 10.1039/C39750000103

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