Issue 2, 1975
From the journal:

Journal of the Chemical Society, Chemical Communications

Novel insertion of acetylene into σ-alkynyl palladium complexes

Y. Tohda,   K. Sonogashira  and  N. Hagihara  

Abstract

trans-[(PEt3)2PdCl(C[triple bond, length half m-dash]CPh)] reacts with di-methyl acetylenedicarboxylate to give an insertion product, trans-[(PEt3)2PdCl {C(CO2Me)[double bond, length half m-dash]C(CO2Me)C[triple bond, length half m-dash]C-Ph}], a type important in acetylene catalytic oligomerisation processes.

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Article information

DOI
https://doi.org/10.1039/C39750000054
Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 54-55

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Novel insertion of acetylene into σ-alkynyl palladium complexes

Y. Tohda, K. Sonogashira and N. Hagihara, J. Chem. Soc., Chem. Commun., 1975, 54 DOI: 10.1039/C39750000054

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