The hydrogen ion-catalysed hydrolysis of thioamides is accelerated by Cu2+ ions which probably from a complex with the usual tetrahedral intermediate and thereby assist leaving group departure.
A. J. Hall and D. P. N. Satchell, J. Chem. Soc., Chem. Commun., 1975, 50 DOI: 10.1039/C39750000050
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