Issue 1, 1975

Reaction of ligating dinitrogen and tetrahydrofuran to form tetrahydropyridazido-complexes

Abstract

In the presence of methyl bromide visible irradiation causes the reaction of tetrahydrofuran with the complexes [M(N2)2(dpe)2](M = W or Mo; dpe = Ph2PCH2CH2PPh2) to form tetrahydropyridazido-complexes [MBr(N2C4H7)(dpe)2] and their hydrobromide salts [MBr(N2C4H8)(dpe)2]Br; in this reaction the ligating dinitrogen appears to have replaced oxygen directly in the tetrahydrofuran ring.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 27-28

Reaction of ligating dinitrogen and tetrahydrofuran to form tetrahydropyridazido-complexes

A. A. Diamantis, J. Chatt, G. A. Heath and G. J. Leigh, J. Chem. Soc., Chem. Commun., 1975, 27 DOI: 10.1039/C39750000027

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