The AlIII-pyridoxal-catalysed threonine aldolase model reactions of threonine and of a new substrate, β-hydroxyvaline, are followed by quantitative n.m.r. measurements in D2O solution; formation of acetone in the β-hydroxyvaline reaction system provides the first quantitative evidence for C–C bond fission of an α-amino-acid having an α-proton in the presence of pyridoxal and metal ions.
J. A. Marcello, A. E. Martell and E. H. Abbott, J. Chem. Soc., Chem. Commun., 1975, 16 DOI: 10.1039/C39750000016
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