The N-alkyl equatorial conformers of 2-methyl-, 2-ethyl-, and 2,3,3-trimethyl-2,3,5,6-tetrahydro-1,4,2-dioxazines predominate, with ΔG°191 values of 1·03, 0·72, and 0·61 kcal mol–1, respectively.
R. A. Y. Jones, A. R. Katritzky, A. R. Martin and S. Saba, J. Chem. Soc., Perkin Trans. 2, 1974, 1561 DOI: 10.1039/P29740001561
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