Issue 12, 1974

Rearrangements in 2-halogeno-3-morpholinothietan 1,1-dioxides. Formation and structure of a cyclic β-sulphonylenamine

Abstract

Refluxing an ethanolic solution of r-2-chloro-t-4-methyl-c-3-morpholino-3-phenyl-(1) and r-2-chloro-c-4-methyl-t-3-morpholino-3-phenyl-thietan 1,1-dioxide (3) ultimately leads to the formation of 3-[2-(2-chloroethoxy)ethyl]-5-methyl-4-phenyl-Δ4-thiazoline 1,1-dioxide via some isomeric intermediates. An X-ray crystallo-graphic analysis of the structure of the Δ4-thiazoline dioxide (8) is reported.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1974, 1483-1487

Rearrangements in 2-halogeno-3-morpholinothietan 1,1-dioxides. Formation and structure of a cyclic β-sulphonylenamine

P. Del Buttero, S. Maiorana, D. Pocar, G. D. Andreetti, G. Bocelli and P. Sgarabotto, J. Chem. Soc., Perkin Trans. 2, 1974, 1483 DOI: 10.1039/P29740001483

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