Ionization constants and u.v. spectra of 3,6-dimercaptopyridazine and its N- and S-methyl derivatives reveal that the parent compound exists in aqueous solution as 3-mercaptopyridazine-6-thione.
3,6-Dihydroxypyridazine, its NN′-dimethyl derivative, and 3-hydroxypyridazine on protonation behave abnormally.
G. B. Barlin, J. Chem. Soc., Perkin Trans. 2, 1974, 1199 DOI: 10.1039/P29740001199
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