The kinetics of the formation and decay of the tetracyanoethylene radical anion from aromatic amine–tetracyanoethylene systems in dichloromethane have been studied. A mechanistic scheme to account for the observed reaction products and kinetic order is proposed and reaction with an excess of donor is suggested to be the major pathway within this mechanism.
P. G. Farrell and P. N. Ngô, J. Chem. Soc., Perkin Trans. 2, 1974, 552 DOI: 10.1039/P29740000552
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