A detailed analysis of the 13C n.m.r. spectra of methyl 4,6-O-benzylidene-D-glycopyranosides (and one ethylidene analogue) and their various C-2 and C-3 derivatives has led to complete assignment of chemical shifts. This study has enabled the effects of a variety of stereochemical features and a variety of functional groups (OH, OMe, O·COR, O·SO2R, NH2, N3) to be established.
E. Conway, R. D. Guthrie, S. D. Gero, G. Lukacs and A.-M. Sepulchre, J. Chem. Soc., Perkin Trans. 2, 1974, 542 DOI: 10.1039/P29740000542
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