Solvolysis of the p-nitrobenzoates of the 9-methyltetracyclo[5.2.1.02,6.04,8]decan-9-ols shows an exo : endo rate of ratio of 2690 : 1 at 25°. This behaviour is the reverse of that exhibited by the corresponding secondary tosylates.
I. Rothberg and R. L. Garnick, J. Chem. Soc., Perkin Trans. 2, 1974, 457 DOI: 10.1039/P29740000457
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