Molecular complexes. Part XIII. Confirmation for methods proposed for rationalizing the processing of data obtained from nuclear magnetic resonance studies

Abstract

The interaction between chloroform and [²H₆]benzene in a variety of inert solvents has been investigated, and the chemical shift data processed using the mole fraction, molar, and molal concentration scales, rationalized, as described previously, to be consistent with the Benesi–Hildebrand method of analysis. It is shown that values obtained for Δ_c for any system are independent of the concentration scale used for its evaluation, and that the values obtained for K_x, K_c, and K_m are theoretically compatible.