Infrared intensities as a quantitative measure of intramolecular interactions. Part XXXIII. Conjugation of substituents with the triple bond in disubstituted acetylenes
Abstract
The integrated intensities of the C
C stretching vibrations are recorded for series of 2-substituted t-butyl- and phenyl-acetylenes. These intensities are related to the resonance effects of the substituents; such resonance interaction is shown to involve both the acetylene π-orbitals.
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