SCHEDULED MAINTENANCE
The rates of hydrolysis of fourteen enaminones at 37° over the pH range 2–11, have been determined. In only five cases was a simple acid catalysed mechanism found to operate and for these, second-order rate constants are presented. In the other examples studied, the plots of first-order rate constant vs.[H+] showed either a maxium or minimum value. Mechanistic interpretations for these observations are made.
K. Dixon and J. V. Greenhill, J. Chem. Soc., Perkin Trans. 2, 1974, 164 DOI: 10.1039/P29740000164
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