Issue 1, 1974

Conformational analysis of cyclohexane derivatives. The A value of a benzyl group

Abstract

At –97·6° the chair–chair equilibrium constant in cis-1-benzyl-4-methylcyclohexane is 1·35, the conformation with an equatorial benzyl group being more stable by 0·11 kcal mol–1. The A value of the benzyl group is 1·81 kcal mol–1.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 2, 1974, 10-13

Conformational analysis of cyclohexane derivatives. The A value of a benzyl group

J. E. Anderson, J. Chem. Soc., Perkin Trans. 2, 1974, 10 DOI: 10.1039/P29740000010

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