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Dienone–phenol rearrangement of steroidal 1,4,6-triene-3,11-diones gives 1-methyl-AB-aromatic steroids, which are oxidised by potassium nitrosodisulphonate to the title compounds. The instability of these quinones is ascribed to their quinone methide character.
S. M. Ali and A. B. Turner, J. Chem. Soc., Perkin Trans. 1, 1974, 2225 DOI: 10.1039/P19740002225
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