Addition to alk-1-enes or alk-1-ynes of the radical obtained from 3,3,4,4-tetrafluoro-4-iodobut-1-ene by either peroxide or metal-salt initiation, provides a convenient route to hex-5-enyl radicals. The size of the rings produced from these radicals is discussed on the basis of the polarisation of the terminal double bond and of the nature of the attacking radical.
P. Piccardi, P. Massardo, M. Modena and E. Santoro, J. Chem. Soc., Perkin Trans. 1, 1974, 1848 DOI: 10.1039/P19740001848
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