Issue 0, 1974

Tautomerism of enamines derived from 2-tetralone. Difference in nucleophilic behaviour between morpholine and pyrrolidine enamines

Abstract

Phenyl isocyanate attacks both the morpholine and the pyrrolidine enamine derived from 2-tetralone at C-1, whereas β-nitrostyrene attacks the former 80% at C-1 and 20% at C-3 and the latter exclusively at C-3. These results confirm the existence of an equilibrium between the 3,4- and 1,4-dihydro-forms of the enamines.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 1625-1627

Tautomerism of enamines derived from 2-tetralone. Difference in nucleophilic behaviour between morpholine and pyrrolidine enamines

G. Pitacco, F. P. Colonna, E. Valentin and A. Risaliti, J. Chem. Soc., Perkin Trans. 1, 1974, 1625 DOI: 10.1039/P19740001625

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