Oxetan-3-ols, formed by the reaction of Grignard reagents with cyclohexanespiro-2′-oxetan-3′-one, rearrange under normal Grignard reaction conditions to 1-acyl-1-hydroxymethylcyclohexanes.
J. A. Donnelly, J. G. Hoey and R. O'Donnell, J. Chem. Soc., Perkin Trans. 1, 1974, 1218 DOI: 10.1039/P19740001218
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