Issue 0, 1974

18-Norandrosta-8,11,13-trienes. Part II. Aromatisation of 18-norandrost-13-enes by bromination and dehydrobromination

Abstract

Bromination of 17,17-disubstituted-18-norandrost-13-enes (1) followed by dehydrobromination gave the corresponding 7,13-dienes (3), which on further bromination and dehydrobromination yielded the 8,11,13-trienes (8). The mechanism of the reaction including the involvement of the 17-substituents is discussed.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 897-903

18-Norandrosta-8,11,13-trienes. Part II. Aromatisation of 18-norandrost-13-enes by bromination and dehydrobromination

C. L. Hewett, I. M. Gilbert, J. Redpath, D. S. Savage, J. Strachan, T. Sleigh and R. Taylor, J. Chem. Soc., Perkin Trans. 1, 1974, 897 DOI: 10.1039/P19740000897

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