Dimethyl trans-cyclopropane-1,2-diacetate (I) and dimethyl trans-oct-4-ene-1,8-dioate (II) failed to undergo cyclisation under the conditions of the modified acyloin reaction. Dimethyl cis- and trans-cyclopropane-1,2-dicarboxylate underwent reductive cleavage with formation of 1,5-dimethoxy-1,5-bis(trimethylsilyloxy)penta-1,4-diene (IV).
C. U. L. Delbaere and G. H. Whitham, J. Chem. Soc., Perkin Trans. 1, 1974, 879 DOI: 10.1039/P19740000879
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