Issue 0, 1974

The constitution of primycin. Part III. Degradation of methylated primycin, and the structure of primycin

Abstract

Methylation of primycin with methyl iodide–silver oxide in dimethylformamide gives a trimethylated urea derivative and a trimethylated guanidine derivative. The cleavage of these products by ozonolysis is described. From a study of the products derived from these reactions a structure is proposed for primycin.

Article information

Article type
Paper

J. Chem. Soc., Perkin Trans. 1, 1974, 836-847

The constitution of primycin. Part III. Degradation of methylated primycin, and the structure of primycin

T. Fehr, R. C. Jain, P. de Mayo, O. Motl, I. Szilagyi, L. Baczynskyj, D. E. F. Gracey, H. L. Holland and D. B. Maclean, J. Chem. Soc., Perkin Trans. 1, 1974, 836 DOI: 10.1039/P19740000836

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