The fragmentation patterns of methanethiol and of 1,1,1-trideuteromethanethiol induced by charge exchange have been studied in a tandem mass spectrometer. The electronic structure has been interpreted using a 304 Å photoelectron spectrum. The results obtained are used to explain the high G-values for the depletion of methanethiol in argon sensitized radiolysis.
B. Jonsson and J. Lind, J. Chem. Soc., Faraday Trans. 2, 1974, 70, 1399 DOI: 10.1039/F29747001399
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