The intensities of the X-ray emission spectra of a series of oxyanions are calculated using ab initio SCF MO wavefunctions, yielding good agreement with the experimental values. When combined with photoelectron spectra, these measurements may allow a definite assignment of the valence ionic states, as in the case of SO2–4, studied here in detail.
J. A. Connor, I. H. Hillier, M. H. Wood and M. Barber, J. Chem. Soc., Faraday Trans. 2, 1974, 70, 1040 DOI: 10.1039/F29747001040
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