Ab initio SCF MO calculations are described for the radicals CH3, CCl3, CF3, SiH3, SiCl3, SiF3, PH+3, PCl+3 and PF+3. The calculated optimized geometries follow the prediction of Pauling using electronegativity arguments, and the calculated hyperfine coupling constants are in moderate agreement with the experimental values.
L. J. Aarons, I. H. Hillier and M. F. Guest, J. Chem. Soc., Faraday Trans. 2, 1974, 70, 167 DOI: 10.1039/F29747000167
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