The modified entrainment method described earlier has been used to study the GaAs/HCl system. Above about 900 K, the principal gallium vapour species is the monochloride, for which ΔH°f298=–63.2 ± 3 kJ mol–1 and S°298= 247 ± 2 J mol–1K–1. Below this temperature, another gallium species thought to be GaCl2 becomes important.
D. Battat, M. M. Faktor, I. Garrett and R. H. Moss, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 2302 DOI: 10.1039/F19747002302
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