Mixtures of methyl and ethyl radicals have been generated at 295 K in a fast flow discharge system by addition of hydrogen atoms to ethylene in helium at total pressures from 6 to 15 Torr (1 Torr = 133 N m–2). Mass spectrometric analysis of the reaction products both with and without added nitric oxide has provided data, numerical analysis of which has given the rate constants of the following reactions, [graphic omitted]
G. Pratt and I. Veltman, J. Chem. Soc., Faraday Trans. 1, 1974, 70, 1840 DOI: 10.1039/F19747001840
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