The solvolysis of methyltin chlorides Me4–xSnClx in highly acidic media has been followed by means of n.m.r. and Mössbauer spectroscopy. Spectral data for the solvated [Me3Sn]+, [Me2Sn]2+, [MeSnCl2]+, and [MeSnCl]2+ cations in solution are reported and discussed.
T. Birchall, P. K. H. Chan and A. R. Pereira, J. Chem. Soc., Dalton Trans., 1974, 2157 DOI: 10.1039/DT9740002157
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