Stretching vibrations of planar di-µ-halogeno-bisdihalogeno-palladate(II) and -platinate(II) anions
Abstract
Raman and i.r. spectra of the anions [M2X6]2–(M = Pd or Pt; X = Cl, Br, or I) in solution are reported. Assignments of the stretching vibrations are proposed. The validity of the use of the descriptions ‘terminal’ and ‘bridging’ to differentiate vibrations in these and related systems is discussed.
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