Extraction equilibria in the zinc nitrate–water–methyl diphenyl phosphate (MePh2PO4) and copper nitrate–water–MePh2PO4 systems have been investigated. The data found are consistent with formation of partially dissociated [Zn(NO3)2(H2O)2(MePh2PO4)3] and [Cu(NO3)2(H2O)3(MePh2PO4)3] complexes. In the case of zinc, the equilibrium constant for complex formation K=(3·6 ± 0·7)× 10–6(mol kg–1 MePh2PO4)–1
A. Apelblat and R. Levin, J. Chem. Soc., Dalton Trans., 1974, 1476 DOI: 10.1039/DT9740001476
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