Issue 7, 1974
From the journal:

Journal of the Chemical Society, Dalton Transactions

Unstable intermediates. Part CXLI. Electron spin resonance spectra of various tin and lead centres in their irradiated salts

Haydn C. Starkie  and  Martyn C. R. Symons  

Abstract

In addition to Sn3+ and Pb3+ centres previously reported, the following have been detected in a range of tin(II) and lead(II) salts after exposure to 60Co γ rays at 77 K: Sn+[in Sn(OAc)2]; Pb+[in Pb(OAc)2]; SnH2+(in SnSO4): PbH2+[in Pb(ClO4)2]; CO2–(Pb2+)[in Pb(HCO2)2]; H2ĊCO2–(Pb2+)[in Pb(MeCO2)2]; and ClO2(Pb2+)[in Pb(ClO4)2]. After attempting to justify these identifications, the electronic structure of these centres is discussed in the light of the e.s.r. parameters.

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Article information

DOI
https://doi.org/10.1039/DT9740000731
Article type
Paper

J. Chem. Soc., Dalton Trans., 1974, 731-735

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Unstable intermediates. Part CXLI. Electron spin resonance spectra of various tin and lead centres in their irradiated salts

H. C. Starkie and M. C. R. Symons, J. Chem. Soc., Dalton Trans., 1974, 731 DOI: 10.1039/DT9740000731

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