Issue 6, 1974

Phosphine–borane derivatives. Part VII. The vibrational spectra of the phosphine adducts of boron trihalides

Abstract

The i.r. and Raman spectra of PH3,BCl3, PD3,BCl3, PH3,BBr3, PD3,BBr3, PH3,BI3, and PD3,BI3 are reported. A normal co-ordinate analysis, utilizing a modified Urey–Bradley force field, confirms the assignments. All the adducts give best fits for a HPH angle of ca. 105–106°.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1974, 595-603

Phosphine–borane derivatives. Part VII. The vibrational spectra of the phosphine adducts of boron trihalides

J. E. Drake, J. L. Hencher and B. Rapp, J. Chem. Soc., Dalton Trans., 1974, 595 DOI: 10.1039/DT9740000595

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