The carbene, cyclopentadienylidene (2), produced by photolysis of diazocyclopentadiene (1) in low-temperature matrices, has been detected by i.r. and u.v. spectroscopy, and its thermal dimerization and reaction with carbon monoxide have been observed.
M. S. Baird, I. R. Dunkin and M. Poliakoff, J. Chem. Soc., Chem. Commun., 1974, 904b DOI: 10.1039/C3974000904B
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