A CNDO/2 molecular orbital study of bifunctional and monofunctional formamidine catalysis of 1,3-proton transfers in propene shows that the energy barrier for bifunctional catalysis is much lower than that for monofunctional catalysis.
H. M. Niemeyer and P. Ahlberg, J. Chem. Soc., Chem. Commun., 1974, 799b DOI: 10.1039/C3974000799B
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