The crystal structure of the title compound has been determined; it contains planar four-membered (Ti–N)2 rings with planar geometry at N which are linked by Cl-bridges, giving five-co-ordinate Ti atoms in approximately trigonal bipyramidal geometry.
N. W. Alcock, M. Pierce-Butler and G. R. Willey, J. Chem. Soc., Chem. Commun., 1974, 627a DOI: 10.1039/C3974000627A
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