The reaction of trans-bis(dinitrogen)bis(bisdiphenylphosphinoethane)molybdenum with tetrakis(ethylthio-µ3-sulphido-ferrate)(2-)
Abstract
We find that no ammonia is formed in the reaction between trans-[Mo(N2)2(dpe)2](dpe = Ph2PCH2CH2PPh2), [Fe4S4(SEt)4]2– and hydrogen chloride, the main products being [MoCl2(dpe)2]+, H2S, EtSH, H2, iron chlorides and, quantitatively, N2.
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