Issue 23, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Synthesis and X-ray crystal structure of cis-[PdCl2{Ph2PCH2CH2P(CF3)2}][cis-1-bistrifluoromethylphosphino-2-(diphenylphosphino)ethane]dichloropalladium(II)

Ljubica Manojlović-Muir,   Douglas Millington,   Kenneth W. Muir,   David W. A. Sharp,   W. Eugene Hill,   James V. Quagliano  and  Lidia M. Vallarino  

Abstract

A novel unsymmetrical ditertiary phosphine, Ph2PCH2CH2P(CF3)2, and its chelate complex cis-[PdCl2{Ph2PCH2CH2P(CF3)2}] have been prepared and characterised; the molecular structure of the latter compound shows that the organic substituents on the phosphorus atoms exert a profound effect on the metal–ligand bonding and that the trans-influence of the PPh2 group is considerably greater than that of the P(CF3)2 group.

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Article information

DOI
https://doi.org/10.1039/C39740000999
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 999-1000

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Synthesis and X-ray crystal structure of cis-[PdCl2{Ph2PCH2CH2P(CF3)2}][cis-1-bistrifluoromethylphosphino-2-(diphenylphosphino)ethane]dichloropalladium(II)

L. Manojlović-Muir, D. Millington, K. W. Muir, D. W. A. Sharp, W. E. Hill, J. V. Quagliano and L. M. Vallarino, J. Chem. Soc., Chem. Commun., 1974, 999 DOI: 10.1039/C39740000999

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