The increase in the ratio of 4,4′-dimethylbibenzyl to 2,5-dimethylbiphenyl formed in the reaction of phenyl radicals with p-xylene with increasing temperature is interpreted as indicating that the formation of 1-phenyl-2,5-dimethylcyclohexadienyl radicals (1) is reversible.
R. Henriquez, A. R. Morgan, P. Mulholland, D. C. Nonhebel and G. G. Smith, J. Chem. Soc., Chem. Commun., 1974, 987 DOI: 10.1039/C39740000987
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