Issue 23, 1974

Micellar general base-catalysed hydrolysis of diphenyl p-nitrophenyl phosphate

Abstract

Micelles of the functional surfactant (II) derived from histidine catalyse the hydrolysis of diphenyl p-nitrophenyl phosphate; deuterium kinetic solvent isotope effects, k(H2O)/k(D2O)ca. 2·5, suggest that (II) acts as a general base rather than as a nucleophilic catalyst.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 971-972

Micellar general base-catalysed hydrolysis of diphenyl p-nitrophenyl phosphate

J. M. Brown, C. A. Bunton and S. Diaz, J. Chem. Soc., Chem. Commun., 1974, 971 DOI: 10.1039/C39740000971

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