Dodecacarbonyltri-iron reacts with 3,3,3-trifluoropropynyldiphenylphosphine to give a trinuclear iron(O) complex having the Fe3(CO)12skeleton, a new type of delocalized 4-carbon chain, a bridging dipheylphosphido-ligand, and a methoxycarbonyl group derived from both the methanol used as a stabilizer for [Fe3(CO)12] and a CO molecule.
H. N. Paik, A. J. Carty, M. Mathew and G. J. Palenik, J. Chem. Soc., Chem. Commun., 1974, 946 DOI: 10.1039/C39740000946
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