Deuterium labelling studies show that 7-cyanobenzocyclo-octene, the major product from the direct irradiation of 2-cyanobenzobarrelene, derives from initial 2π+ 2π bonding between the vinyl and vinylcyano units.
C. O. Bender and S. S. Shugarman, J. Chem. Soc., Chem. Commun., 1974, 934 DOI: 10.1039/C39740000934
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