An inversion of 3-H analogous to that required in vivo has been found to occur spontaneously under mild conditions during a synthesis of Corynanthé-type alkaloids from a vincoside derivative.
R. T. Brown, C. L. Chapple, R. Platt and H. Spencer, J. Chem. Soc., Chem. Commun., 1974, 929 DOI: 10.1039/C39740000929
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