Issue 22, 1974
From the journal:

Journal of the Chemical Society, Chemical Communications

Evidence from the photoelectron spectra of some mercury(II) compounds for the involvement of the inner 5d electrons in covalent bonding

Peter Burroughs,   Stephen Evans,   Andrew Hamnett,   Anthony F. Orchard  and  Neville V. Richardson  

Abstract

Structure corresponding to ionisation of the inner 5d electrons, observed in the He-I photoelectron spectra of HgMe2, MeHgCN, and Hg(CN)2, provides evidence for dπ→π* back-donation in the Hg–CN bond; dz2–s hybridisation is apparently not a strong effect.

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Article information

DOI
https://doi.org/10.1039/C39740000921
Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 921-922

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Evidence from the photoelectron spectra of some mercury(II) compounds for the involvement of the inner 5d electrons in covalent bonding

P. Burroughs, S. Evans, A. Hamnett, A. F. Orchard and N. V. Richardson, J. Chem. Soc., Chem. Commun., 1974, 921 DOI: 10.1039/C39740000921

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