Absolute configurations of the enantiomers of threo-2-methyltartaric acid and 2,3-dimethyltartaric acid have been determined from stereoselective differences observed in the extent of binding at a chiral vanadyl(IV) site; the method can also rapidly distinguish between erythro and threo isomers and is applicable to other substituted tartaric acids.
S. K. Hahs and R. E. Tapscott, J. Chem. Soc., Chem. Commun., 1974, 791 DOI: 10.1039/C39740000791
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